Analytical Modeling of CO2 Migration in Saline Aquifers for Geological CO2 Storage

Injection of carbon dioxide into geological formations for long-term storage is widely regarded as a promising tool for reducing global atmospheric CO2 emissions. Given the environmental and health risks associated with leakage of CO2 from such a storage site, it is critical to ensure that injected CO2 remain trapped underground for the foreseeable future. Careful site selection and effective injection methods are the two primary means of addressing this concern, and an accurate understanding of the subsurface spreading and migration of the CO2 plume during and after injection is essential for both purposes. It is well known that some CO2 will be trapped in the pore space of the aquifer rock as the plume migrates and spreads; this phenomenon, known as capillary trapping, is an ideal mechanism for geological CO2 storage because the trapped gas is immobile and distributed over a large area, greatly decreasing the risk of leakage and enhancing the effectiveness of slower, chemical trapping mechanisms. Here, we present an analytical model for the post-injection spreading of a plume of CO2 in a saline aquifer, both with and without capillary trapping. We solve the governing equation both analytically and numerically, and a comparison of the results for two different initial plume shapes demonstrates the importance of accounting for the true initial plume shape when capillary-trapping effects are considered. We find that the plume volume converges to a self-similar, power-law trend at late times for any initial shape, but that the plume volume at the onset of this late-time behavior depends strongly on the initial shape even for weakly trapping systems. Thesis Supervisor: Ruben Juanes Title: Assistant Professor, Civil and Environmental Engineering Thesis Reader: Anette E. Hosoi Title: Associate Professor, Mechanical Engineering